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Beilstein J. Org. Chem. 2011, 7, 543–552, doi:10.3762/bjoc.7.62
Graphical Abstract
Figure 1: Molecular structures of syn-isobutyl chloroformate (1), syn-isobutyl chlorothioformate (2), phenyl ...
Scheme 1: Stepwise addition–elimination mechanism through a tetrahedral intermediate for solvolysis of chloro...
Scheme 2: Unimolecular solvolytic pathway for the dithioformate esters.
Figure 2: The plot of log (k/k0) for iBuOCOCl (1) against log (k/k0) for PhOCOCl (3).
Figure 3: The plot of log (k/k0) for isobutyl chloroformate (1) against 1.82 NT + 0.53 YCl in eighteen pure a...
Figure 4: The plot of log (k/k0) for isobutyl chlorothioformate (2) against 0.42 NT + 0.73 YCl in 15 pure and...